E150d: Sulfite Ammonia Caramel (Class IV Caramel) vs. E224: Potassium Metabisulfite (Campden Salt)
Comparing 2 standards across 10 specifications. 10 key differences identified.
E150d (Class IV Caramel) is prepared by heating carbohydrates with both sulfite and ammonium compounds, creating an intensely dark, negatively charged colloid. INS 150d, group ADI is 300 mg/kg bw/day, the global color standard in cola soft drinks.
E224 (Potassium Metabisulfite / K2S2O5) is a white crystalline powder releasing 57.6% sulfur dioxide by weight when dissolved in acidic liquids. INS 224, ADI is 0.7 mg/kg bw/day, the premier sanitizing and stabilizing agent in commercial winemaking.
Specification Comparison Table
10 Parameters| Parameter / Spec | ||
|---|---|---|
|
E-Number Code
|
E150d | E224 |
|
INS / Codex Number
|
INS 150d | INS 224 |
|
Functional Class
|
Food Color (Deep Brown / Black) | Preservative, Antioxidant, Sanitizer |
|
Acceptable Daily Intake (ADI)
|
300 mg / kg body weight per day (Group ADI for caramel colors) | 0.7 mg / kg body weight per day (as SO2 equivalent) |
|
Primary Mechanism
|
High tinctorial power melanoidin polymers soluble and stable in carbonated phosphoric acid matrix | Releases free SO2 and potassium ions, neutralizing wild yeasts and preventing enzymatic must oxidation |
|
Common Target Foods
|
Cola soft drinks, dark beers/stouts, gravies, pet foods, soy sauce | Grape must, commercial wines, ciders, lemon juice concentrates, dried fruit processing |
|
Dietary Compliance
|
Vegan (Sugar/syrup base), Halal, Kosher | Vegan, Halal, Kosher (Allergen labeling required) |
|
Safety Approval
|
EFSA Authorized / FDA GRAS (Strictly controlled 4-MEI limits) | EFSA Authorized / FDA GRAS (21 CFR 182.3637) |
|
Isoelectric Point & Charge
|
Strong negative colloidal charge (pH 0.5–2.0) preventing precipitation in acid sodas | — |
|
Chemical Formula
|
— | K2S2O5 |