E150a: Plain Caramel (Class I Caramel Color) vs. E150d: Sulfite Ammonia Caramel (Class IV Caramel)
Comparing 2 standards across 10 specifications. 10 key differences identified.
E150a (Class I / Plain Caramel) is produced by controlled thermal heating of food carbohydrates without ammonium or sulfite compounds. INS 150a, ADI is Not Specified, yielding a warm brown-amber color in spirits, whiskey, and vinegars.
E150d (Class IV Caramel) is prepared by heating carbohydrates with both sulfite and ammonium compounds, creating an intensely dark, negatively charged colloid. INS 150d, group ADI is 300 mg/kg bw/day, the global color standard in cola soft drinks.
Specification Comparison Table
10 Parameters| Parameter / Spec | ||
|---|---|---|
|
E-Number Code
|
E150a | E150d |
|
INS / Codex Number
|
INS 150a | INS 150d |
|
Functional Class
|
Food Color (Brown), Aromatic Flavoring | Food Color (Deep Brown / Black) |
|
Acceptable Daily Intake (ADI)
|
Not Specified (Quantum Satis / Highest purity class) | 300 mg / kg body weight per day (Group ADI for caramel colors) |
|
Primary Mechanism
|
Pyrolysis and non-enzymatic caramelization forming high-molecular-weight chromophores | High tinctorial power melanoidin polymers soluble and stable in carbonated phosphoric acid matrix |
|
Common Target Foods
|
Scotch whisky, bourbon, brandy, rum, balsamic vinegar, craft ales | Cola soft drinks, dark beers/stouts, gravies, pet foods, soy sauce |
|
Dietary Compliance
|
100% Vegan (Sugar derived), Halal, Kosher, 4-MEI Free | Vegan (Sugar/syrup base), Halal, Kosher |
|
Safety Approval
|
EFSA Authorized / FDA GRAS (21 CFR 73.85) | EFSA Authorized / FDA GRAS (Strictly controlled 4-MEI limits) |
|
Chemical Class
|
Complex polymeric carbohydrate breakdown caramelans, caramelens, caramelins | — |
|
Isoelectric Point & Charge
|
— | Strong negative colloidal charge (pH 0.5–2.0) preventing precipitation in acid sodas |